The clip was posted to The Late Late Show's official Instagram account with the caption:
"@chrishemsworth and James had a competition to see who was a better waiter and it was absolute chaos."
The post quickly racked up over 300,000 views and hundreds of comments from delighted social media users.
International football star David Beckham couldn't contain his amusement at the skit, leaving a string of laughing emojis in the comments section.
Earlier this month, Chris revealed what it felt like saying goodbye to his career defining role, Thor, after filming for the final installment of the legendary Avengers franchise wrapped last year.
Speaking to KIIS 106.5's Kyle and Jackie O from Bali, he joked: "It wasn't until weeks after that I realised I was unemployed."
"There was certainly a bittersweet quality to the whole wrapping up of it all - it was 10 years of my life, you know. It's been the most prominent character and film journey I've been on, I've a huge amount of pride [for it].
"It was kind of like high school, saying goodbye to everyone and saying goodbye to my character. I just loved [playing] that character."
The Marvel star said he's held onto some of Thor's trademark props including his beloved hammer, which he plans to auction for charity.
Chris also revealed his wife, Spanish model Elsa Pataky, is sick of his constant shirtless appearances on screen, joking: "She's just like, put your clothes on!"