"I'm thrilled to be the face of Deep Euphoria Calvin Klein," Robbie said in a statement.
"This is my first advertising campaign and I am honoured it is with Calvin Klein, an iconic brand I have known and loved for many years."
Melisa Goldie, chief marketing officer for Calvin Klein, describes "Calvin Klein women” as “provocative and liberated”, saying that “the Deep Euphoria woman embodies all of these facets with an added layer of adventure.”
Robbie's new film The Legend of Tarzan is currently in cinemas. Deep Euphoria will be available around the world next month.