Sporting a stylish fedora hat and hugging adopted daughter, August, 43-year-old Charlize looked mellow in yellow as she enjoyed a day out at the the Farmers Market in Studio City.
Meanwhile, 55-year-old Brad was pictured just hours later looking cool and casual getting into his car following a meeting in Beverly Hills.
The pair, who have known each other for years through mutual industry pals, reportedly grew close while working together on a recent photo shoot for Swiss watch company Breitling.
Other reports suggest the talented couple were introduced by Charlize's ex, fellow actor Sean Penn.